One-Step DMT Synthesis
by WizardX
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Cyclisation reaction involving nitro- and nitroso- groups with tervalent phosphorus compounds.
Reaction with 2-(2-nitrophenyl)-4-dimethylamine butene:
(2-NO2)C6H4-C(CH2CH2N(CH3)2)=CH2 
DMT 58 %
Reaction with 2-Nitrostyrene:
(NO2)C6H4-CH=CH2 Indole
A good starting compound for 2-(2-nitrophenyl)-4-dimethylamine butene would be 2-nitrocinnamic aldehyde.
References
[1] [reducing agents] Quart. Rev. , Vol 16, pg 208 (1962)
[2] [reduction of -NO and -NO2] Quart. Rev. , Vol 22, pg 222 (1968)
[3] [Deoxygenation reactions : Cyclisation] Chem. Soc. Rev. , Vol 3, pg 87 (1974)
